Product ID:UNOCAL UNLEADED PLUS 87 M/H GRADE; PRODUCT
MSDS Date:04/17/1991
FSC:9130
NIIN:01-282-2844
MSDS Number: BPQZX

UNION OIL CO OF CALIFORNIA UNOCAL CHEMICALS DIV

1201 W 5TH ST
LOS ANGELES, CA 90060
US

Emergency Phone: 800-424-9300(CHEMTREC)/503-641-3222

Info Phone: 213-977-7589

Cage: 23034

76 PRODUCTS CO

LOS ANGELES, CA 90017 US

Telephone: 213-977-7589

Cage: 23034

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1-5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 1-9%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 1-14%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1-5%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 1-5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9293

LD50 LC50 Mixture:TLV: 300 PPM (8-HOUR)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYES-MILD EYE IRRITATION. SKIN-MILD
SKIN IRRITATION. INHALATION-BREATHING HIG CONCENTRATIONS MAY CAUSE
LOSS OF CONSCIOUSNESS, CONVULSION, RESPIRATORY COLLAPSE & DEATH.
INGESTION-ASPIRATION HAZARD. THI S MATERIAL CAN ENTER LUNGS DURING
SWALLOWING OR VOMITING & CAUSE LUNG INFLAMMATION & DAMAGE.
Explanation of Carcinogenicity:BENZENE, A COMPONENET OF THIS PRODUCT,
IS A KNOWN CANCER (LEUKEMIA) HAZARD.
Effects of Overexposure:EYES: STINGING, TEARING AND REDNESS. SKIN:
DREDNESS, BURINIG, & DRYING AND CRACKING OF THE SKIN. INHALE:
FLUSHING, BLURRED VISION, NAUSEA, HEADACHE, DIZZINESS, DROWSINESS,
LOSS OF CORDINATION & FATIDU E. INGESTION: IRRITATION OF THE
DIGESTIVE TRACT, HEADACHE, DROWSINESS, DIZZINESS, LOSS OF
COORDINATION, & FATIGUE.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN &
LUNG DISORDERS MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS
MATERIAL.

First Aid:EYE-REMOVE FROM EXPOSURE. FLUSH EYES WITH CLEAN WATER. IF
IRRITATION PERSISTS, SEE A DOCTOR. SKIN-WIPE MATERIAL FROM SKIN.
WASH SKIN THOROUGHLY WITH SOAP & WATER. INHALATION-IF SYMPTOMS
OCCUR, MOVE TH E PERSON TO FRESH AIR. IF STOP BREATHING, DO CPR.
CALL A DOCTOR. INGESTION-ASPIRATION HAZARD. DO NOT INDUCE VOMITING
OR GIVE ANYTHING BY MOUTH. IF UNCONSCIOUS PLACE VICTIM ON LEFT
SIDE. CALL A DOCTOR.

Flash Point Method:TCC
Flash Point:-45F,-43C
Autoignition Temp:Autoignition Temp Text:UNK
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, FOAM OR WATER
SPRAY. WATER MAY BE INEFFECTIVE.
Fire Fighting Procedures:WEAR APPROPIATE PROTECTIVE EQUIPMENT INCLUDING
RESPIRATORY PROTECTION AS CONDITIONS WARRANT.USE WATER SPRAY TO
MINIMIZE OR DISPERSE VAPORS & COOL EQUIPMENT.
Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL CONSIDERABLE DISTANCES
TO IGNITION SOURCES, IGNITE, FLASHBACK OR EXPLODE. VAPOR/AIR
EXPLOSION HAZARD INDOORS/OUTDOORS OR IN SEWERS.

Spill Release Procedures:EXTREMELY FLAMMABLE. ELIMINATE ALL SOURCES OF
IGNITION. STAY UPWIND. ISOLATE AREA. STOP SPILL WITHOUT RISK. WEAR
APPROPIATE PROTECTIVE EQUIPMENT INCLUDING RESPIRATORY PROTECTION AS
CONDITION WARRANT. PREVENT SPILL FROM ENTERING WTAER, SEWERS,
DRAINS.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. USE &
STORE THIS MATERIAL IN COOL, DRY, WELL VENTILATED AREAS AWAY FROM
HEAT, DIRECT SUNLIGHT & SOURCES OF IGNITION.
Other Precautions:BOND AND GROUND ALL MATERIAL WHEN TRASNFERRING FROM
ONE CONTAINER TO ANOTHER. PROTECT CONTAINERS FROM PHYSICAL DAMAGE.
USE EXPLOSION-PROOF EQUIPMENT. POST AREA "NO SMOKING OR OPEN
FLAME."

Respiratory Protection:THE USE OF RESPIRATORY PROTECTION IS ADVISED
WHEN CONCENTRATIONS EXCEED THE ESTABLISHED EXPOSURE LIMITS.
DEPENDING ON THE AIRBORNE CONCENTRATION, USE A RESPIRATOR OR GAS
MASK WITH APPROPIATE CARTRIDGE & CANNISTER OR SUPPLIED AIR
EQUIPMENT.
Ventilation:IF CURRENT VENTILATION ISN'T ADEQUATE, ADDITIONAL
VENTILATION OR EXHASUT SYSTEM MAY BE REQUIRED.
Protective Gloves:WEAR IMPERMEABLE GLOVES.
Eye Protection:APPROVED EYE PROTECTION IS RECOMMENDED.
Other Protective Equipment:IT IS SUGGESTED THAT A SOURCE OF CLEAN WATER
BE AVALIABLE IN THE WORK AREA FOR FLUSHING EYE/SKIN. WEAR
IMPERVIOUS CLOTHG
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
DANGER!! EXTREMELY FLAMMABLE. VAPORS MAY EXPLODE. HARMFUL OR FATAL IF
SWALLOWED. VAPOR HARMFUL. ASPIRATION HAZARD IF SWALLOWED. CAN ENTER
LUNGS AND CAUSE DAMAGE. POSSIBLE CANCER HAZARD BASED ON TEST W ITH
LAB ANIMALS. NO SMOKING OR OPEN FLAME. KEEP AWAY FROM HEAT, SPARKS,
OPEN FLAMES & STATIC ELECTRICITY.

HCC:F1
Boiling Pt:B.P. Text:90-430F
Melt/Freeze Pt:M.P/F.P Text:NA
Decomp Temp:Decomp Text:NANOT GIVEN
Vapor Pres:NA
Vapor Density:>1 AIR=1
Spec Gravity:0.75
pH:NA
Viscosity:NA
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUID. GASOLINE ODOR.
Percent Volatiles by Volume:100%
Corrosion Rate:NA

Stability Indicator/Materials to Avoid:YES
CONTACT WITH STRONG OXIDIZING AGENTS SUCH AS CHLORINE, PERMANGANATES &
DICHROMATES MAY CAUSE FIRE OR RXPLOSION.
Stability Condition to Avoid:AVOID ALL POSSIBLE SOURCES OF IGNITION.
Hazardous Decomposition Products:COMBUSTION MAY YIELD CARBON MONOXIDE &
SMALL AMOUNTS OF OXIDES OF SULFUR & NITROGEN, BENZENE & OTHER
ORGANIC COMPOUNDS.

Waste Disposal Methods:DISDPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL,
STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.